For a short reminder about ordered fields you can have a look to following post. We prove there that Q can be ordered in only one way.
That is also the case of R as R is a real-closed field. And one can prove that the only possible positive cone of a real-closed field is the subset of squares.
Let K be a field. An ordering of K is a subset P of K having the following properties:
ORD 1
Given x∈K, we have either x∈P, or x=0, or −x∈P, and these three possibilities are mutually exclusive. In other words, K is the disjoint union of P, {0}, and −P.